Batteries react differently in different
temperatures.While some batteries are engineered to work well in colder
temperature, most have decreased output in colder temperatures. This is
because of the nature of chemical reactions. In a reaction, you can
change the speed of a reaction by adding heat. Alternatively, you can
do the reverse by cooling it down. By adding more heat to a system, the
particles move faster and collide more often, making it easier for
bonds to break and reform. With the chemical reactions progressing at a
slower rate, less current is produced. As voltage and current are
directly proportional, the amount of voltage supplied is also decreased.
To avoid this energy loss, you simply have to heat up the battery
before use in colder weather. If the battery is already warm, it will
continue to stay warm to some extent, since heat is produced as a waste
product. The lower the temperature, the less effective this is. Some
electronics are designed to output heat to keep the battery warm. Most
are not.
On a side note, cars have this same problem at times. In Europe, many
cars are built with the battery inside the vehicle to help keep the
battery warmer.
Cold weather also effects batteries in another negative way. In cold
temperatures, the connections will actually contract, leaving the
battery with less contact area at the battery terminals. As a result,
there is voltage loss between the terminals.
image from http://www.alibaba.com
In extremely cold temperatures, batteries will freeze, resulting in
zero output voltage.
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