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    Electricity is a form of energy, described as the flow of electrons between atoms.  Atoms are described to be arranged such that electrons are contained within shells around the the nucleus.  The nucleus lies at the center of these shells, packed with protons and neutrons.  The protons exert a positive electrical charge while the electrons exert a negative electrical charge, the resulting attractive electric force is responsible for what holds together an atom.  The number of protons within the nucleus determines what element it is, since the number of protons doesn't change.  Within each shell there are a certain number of energy slots. which can be filled with an electron.  When a shell of an atom is filled, the electrons begin to fill the next shell.  While the electrons within the filled shells are more stable, remainder electrons in the last shell are loosely attracted to the atom and can be exchanged with other atoms.  An atom is charged when electrons are exchanged, referred to as ionization, causing the atom to either become positively charged when removed or negatively charged with the addition of electrons. 
   
Example of atomic shells of Na                       An Example of atomic shells (Na)
Photo Credit: http://homepages.ius.edu/GKIRCHNE/Chem.htm