what is glass exactly?




The physics community seems to be divided about what exactly glass is, but for the mean time it has been labeled an amorphous solid. Essentially it is any material that has been super cooled such that it has the properties of a glass, primarily that it appears to have many of the properties of a solid, but microscopically it looks exactly like a liquid (as demonstrated in the image to the right).


When I say it looks like a liquid I mean that the molecules are disorderly. Traditional solids form crystalline structures as they harden (think glass or stalactites), but glass does not. Glass is formed when you cool a liquid quickly and the molecules loose energy to fast to form proper crystalline latices. As Robert Kunzig poetically puts it in his discover magazine article The Physics of...Glass:

"As the temperature drops, the liquid becomes more viscous and the molecules more sluggish. Its like a game of musical chairs in which the music never stops and the players never sit down; instead they seem to move through honey, then tar, until they are but motionless, like bugs in amber."


Generally the slower you cool something (that still results in glass) the more dense (and the more break resistant) the resulting glass. Although since the less viscous a liquid is at its cooling point the less like it is to become glass depending on the material this slower cooling rate may just mean it becomes a proper solid instead.

The really intriguing thing about glass, and another part of the reason it can't quite be considered a new state of matter, is that once formed glass is never in equilibrium, while all other states of matter are.

Note: glass was initially formed into things like windows by being stretched into a long string and then beaten until it was mostly flat by glassblowers. This resulted in wavy windowpanes with thicker edges (this is where the myth that glass is a liquid comes from, since the thicker edges give the appearance that the glass has dripped down the windowpane slightly). Nowadays though typical flat ordinary glass, and some of the glass that will become tempered and or laminated glass is formed by a process called floating, where it is poured over a vat of molten tin. This produces much more uniform and flat sheets of glass.

source: The glass phase: a physics mystery (tue.nl)




source: How Glass Is Made - YouTube