Chemistry of Explosives

Explosives are classified as substances that undergo an exothermic reaction at a very quick rate. These reactions are all characterized by a higher quantity of gas phase products than reactants. This increase in particles as well as the increase in heat released from the chemical bonds is what causes the expansion (explosion) for conventional explosives. For low explosives this means that the required chemicals are available for combustion in the explosive itself. This way the rate of combustion is quick enough to provide an explosion if it is kept in a small container (such as gun powder in a gun barrel). High explosives in contrast can either be a reaction that occurs between two chemicals like in low explosives or a decomposition of one chemical into multiple chemicals. The increase in rate of combustion or decomposition causes the energy released into the particles and heat to move faster than the speed of sound. Because the energy cannot be transferred fast enough by the surrounding medium (air) the energy is built up and passed along moving at the maximum possible velocity for that medium (speed of sound). It is this phenomenon that causes the shock wave from explosions.

For thermonuclear devices the primary source of energy released in the explosion comes from the fission or fusion reaction that takes as the bomb detonates. When compared to the power of conventional bombs, the energy released by a nuclear bomb easily dwarfs a normal bomb. For example the first ever nuclear bomb dropped was code named "Little Boy" and exploded with the force of 15,000 tons of TNT. The largest nuclear weapon every dropped was the "Tsar Bomba" and it exploded with the force of 50 megatons of TNT. On google earth you can still see the crater from where it landed (as it blew away a good chunk of an island). Originally the Tsar was intended to be a 100 megaton bomb but it was scaled down due to concerns of radiation fall out.

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