Application
- Aromatic ring current has a huge effect on NMR
(Nuclear Magnetic Resonance) spectroscopy
- This is a very sophisticated and modern way of
identifying organic chemical compounds by using
magnetic pulses to find a compounds physical and
chemical properties. Specifically its hydrogen
(proton) and carbon properties.
- Since aromatic rings have a current and
therefore a magnetic field they act differently
when hit with a magnetic pulse than non aromatic
organic compounds.
- The magnetic field induced by the ring current
causes the electrons of the hydrogen's on the
outside to deshield and the result is that the
hydrogen show up farther down field in an NMR
spectrum.
- This allows chemists to easily identify aromatic
structures based on the NMR spectrum.
http://orgchem.colorado.edu/Spectroscopy/specttutor/imagesarom/tol.gif
This is an HNMR spectrum of toluene, which is an
aromatic compound. The peak on the left with a 5 above
it represents the 5 hydrogen that are attached to the
aromatic ring. They are so far down field because of
the induced magnetic field due to the current compared
to the three hydrogen attached to the methyl group.
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