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www.howstuffworks.com
A stout like Guinness has a creamier, longer lasting head than a canned
lager beer. In addition, Guinness is less fizzy than a regular lager
beer. Guinness is canned with a mixture of carbon dioxide and nitrogen.
Nitrogen is not absorbed into the beer nearly as well as carbon dioxide,
so even though a can of Guinness may be at the same pressure as a can
of lager, it contains less CO2 (and is therefore less fizzy) because
the nitrogen makes up some of the pressure.
Because a beer like Guinness contains less dissolved CO2, if you poured
it from a can with no widget, the head not be very thick because most
of the CO2 would stay dissolved.
The purpose of the widget is to release the CO2 from some of the beer
in the can to create the head. The widget is a plastic, nitrogen-filled
sphere with a tiny hole in it. The sphere is added to the can before
the can is sealed. It floats in the beer, with the hole just slightly
below the surface of the beer.
Just before the can is sealed a small shot of liquid nitrogen is added
to the beer. This liquid nitrogen evaporates during the rest of the
canning process and pressurizes the can. As the pressure increases in
the can, beer is slowly forced into the sphere through the hole, compressing
the nitrogen inside the sphere.
When you open the can, the pressure inside immediately drops, the compressed
gas inside the sphere quickly forces the beer out through the tiny hole
into the can. As the beer rushes through the tiny hole, this agitation
causes the CO2 that is dissolved in the beer to form tiny bubbles that
rise to the surface of the beer. These bubbles help form the head.